Vol 25, No 1

A Method to Assess the Applicability and Accuracy of the Modified Gaussian Model (MGM) on the Rock Samples' Spectral Interpretation

Fang Gao, Bin Liu, Qin Zhou and Chun-Lai Li

Abstract

The Chang'e-4 mission obtained spectral data of multiple rock targets on the lunar surface. The Modified Gaussian Model (MGM) is usually applied to the spectral interpretation of powder samples, its applicability and accuracy on the rock targets remain to be further evaluated. The rock slice of lunar meteorite NWA 4734 is used to conduct comprehensive analysis of the petrography, mineralogy and laboratory spectroscopy, which will provide important ground truth for the MGM interpretation of lunar in situ spectra of rock samples. First, a scanning electron microscope (SEM), Energy Dispersive Spectrometer (EDS), and Electron Probe Micro-Analyzer (EPMA) analysis results indicate that: (1) almost all plagioclase in NWA 4734 have been converted to maskelynites, which indicate that the meteorite has undergone severe impact metamorphism; (2) the chemical composition of pyroxene and olivine is significantly heterogeneous, showing a distribution characteristic of magnesium-rich core and iron-rich rim, further indicating that NWA 4734 has undergone multiple crystallization and differentiation. Second, this article focuses on the rock slice of NWA 4734's greyscale image of the Back Scattering Electron (BSE), and obtains the proportion of High-Calcium Pyroxene (HCP) in the total pyroxenes of this sample by calculating the area percentage using the pixel counting method. The result shows that the proportion of HCP is 72% ± 5.4%, which can be used as a ground truth to evaluate the interpretation applicability and accuracy of MGM. A field spectrometer (ASD) is used to measure the visible and near-infrared reflectance spectra (450–2500 nm) of the rock slice from NWA 4734 in the same area as the BSE image obtained by SEM, and MGM is used to deconvolve the ASD spectra, and the average proportion of HCP is estimated to be 71% ± 10.1%. The results between the MGM and the pixel counting are comparable within the error range, which demonstrates the applicability of MGM on interpretation of the rock samples on the lunar surface.

Keywords

Key words: astrochemistry– methods: data analysis– instrumentation: spectrographs

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